https://ogma.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 Conformation of poly(ethylene oxide) dissolved in the solvate ionic liquid [Li(G4)]TFSI https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:23022 g) and viscosity as a function of polymer concentration allow the overlap concentrations, c* and c**, to be identified at 13 mg mL⁻¹ and 50 mg mL⁻¹, respectively, which are similar to values reported previously for conventional ionic liquids. Unlike water and conventional ionic liquids, [Li(G4)]TFSI cannot form hydrogen bonds with PEO. Thermal gravimetric analysis indicates that the solvation of PEO by [Li(G4)]TFSI is a consequence of PEO forming coordinate bonds with the lithium by displacing the anion, but without displacing the glyme molecule.]]> Wed 11 Apr 2018 15:11:45 AEST ]]> Conformation of poly(ethylene oxide) dissolved in the solvate ionic liquid [Li(G4)]TFSI https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:27045 g) and viscosity as a function of polymer concentration allow the overlap concentrations, c* and c**, to be identified at 13 mg mL(-1) and 50 mg mL(-1), respectively, which are similar to values reported previously for conventional ionic liquids. Unlike water and conventional ionic liquids, [Li(G4)]TFSI cannot form hydrogen bonds with PEO. Thermal gravimetric analysis indicates that the solvation of PEO by [Li(G4)]TFSI is a consequence of PEO forming coordinate bonds with the lithium by displacing the anion, but without displacing the glyme molecule.]]> Wed 11 Apr 2018 10:55:18 AEST ]]>